Mental Model
Use a stack to keep numbers until an operator appears, then combine the last two numbers using that operator.
Analogy: Imagine a stack of plates where you add plates with numbers. When you see a math sign, you take the top two plates, do the math, and put the result back on top.
Stack (top at right): [] Postfix expression: 2 3 + 4 * Numbers push in order, operators combine top two numbers.