In JavaScript global scope, the keyword 'this' refers to the global object. In browsers, this global object is the Window object, so 'this' points to Window. In Node.js, 'this' in the global scope points to the global object. When you declare a variable with 'var' globally, it becomes a property of this global object, so you can access it using 'this.variableName'. However, variables declared with 'let' or 'const' do not attach to the global object and cannot be accessed via 'this'. This behavior is shown in the execution table where 'this' is logged, then a variable 'a' is declared with 'var', and finally 'this.a' outputs 10 in both browser and Node.js. Understanding this helps avoid confusion about what 'this' means in different environments and how global variables relate to it.