Boundary traversal of a binary tree collects nodes on the outer edge in anti-clockwise order. We start at the root, add it to the boundary list. Then we traverse the left boundary from top to bottom, adding only non-leaf nodes. Next, we add all leaf nodes from left subtree and right subtree in left to right order. Finally, we traverse the right boundary from bottom to top, adding non-leaf nodes. This order ensures the boundary is collected without duplicates and in correct anti-clockwise order. The execution table shows each step with nodes visited and how the boundary list grows. Key moments clarify why leaves are added separately and why right boundary is added bottom-up. The visual quiz tests understanding of these steps and the final boundary list.