Row-level security policies in PostgreSQL control access to rows in a table based on conditions. First, you enable RLS on the table. Then, you create a policy that defines which rows a user can see, for example, rows where the department matches the user's current department. When a user queries the table, PostgreSQL checks each row against the policy condition. Only rows that satisfy the condition are included in the result. Rows that do not match are excluded. This filtering happens automatically once RLS is enabled and policies are defined. You can set session variables to customize the policy condition dynamically. This way, users only see data they are allowed to access, improving security and data privacy.