DISTINCT ON in PostgreSQL helps select one unique row per group. It works by sorting the table rows by the group column(s) and other criteria, then scanning top to bottom. For each group, it keeps only the first row it sees and skips the rest. This way, you get one row per group, for example, the highest priced product in each category. The ORDER BY clause is very important because it controls which row is first per group. The execution table shows step-by-step how rows are read and either kept or skipped. Beginners often wonder why some rows are skipped or why ORDER BY matters; the execution steps clarify these points. This feature is handy for queries needing unique groups with a preferred row, but remember it is specific to PostgreSQL.