The Two Pointer Technique on Arrays uses two indexes starting at the beginning and end of the array. We check if the left pointer is less than the right pointer. If yes, we process the elements at these pointers, then move the left pointer right and the right pointer left. This repeats until the pointers meet or cross, stopping the loop. This technique helps efficiently process pairs or search in sorted arrays. The example code prints pairs from the outside moving inward. The pointers start at 0 and array length minus one, printing elements at these positions, then moving inward until they meet at the middle. The loop stops when left is no longer less than right, avoiding double processing of the middle element in odd-length arrays.