Mental Model
We group tree nodes by their vertical columns and list nodes top to bottom in each column.
Analogy: Imagine standing in front of a tree and looking straight at it. Nodes that line up vertically form a column. We read nodes column by column from left to right, and within each column from top to bottom.
1
/ \
2 3
/ \ \
4 5 6
Columns: -2 -1 0 1
Nodes: 4 2 1 5 3 6