Enqueue operation in a linked list queue involves creating a new node with the given data and next pointer set to NULL. If the queue is empty, both head and tail pointers are set to this new node. Otherwise, the current tail's next pointer is linked to the new node, and then tail is updated to point to the new node. This process ensures the queue grows at the tail end, maintaining FIFO order. The execution table shows each step with pointer updates and the visual linked list state. Key moments clarify why checking tail for NULL is important, why tail->next must be updated before tail, and why newNode->next must be NULL to avoid list corruption.