In Angular, form validation with template attributes works by adding validation rules directly in the HTML input elements. For example, 'required' and 'email' attributes tell Angular what to check. Angular tracks the input's validity and whether the user has interacted with it using a template reference variable like #emailRef. When the user types and leaves the input, Angular marks it as touched. If the input is invalid and touched, an error message appears. The form submission button is enabled only when all validations pass. This method is easy to use and keeps validation logic close to the input fields.